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Angeline Jolie has filed for divorce from Brad Pitt,Annette Haven in Peaches and Cream porn movie (1981) her attorney confirmed Tuesday, bringing an end to one of the biggest celebrity couples of the new millennium.

SEE ALSO: Brangelina isn't alone: 6 more couples who broke up after making movies together

Here's a look at the life they shared in pictures, from the early days a decade ago to their last moments in the public eye together.

June 2005: 'Mr & Mrs Smith' premiere

Brangelina began just over ten years ago, when the pair met on the set of Mr & Mrs Smith in 2004. Pitt was still married to Jennifer Aniston at the time, but they split in January 2005. Before long the speculation began. In April of that year, the couple was spotted for the first time on a beach in Kenya.

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Pitt and Jolie were later pictured at the premiere of their movie at the Mann Village Theater in June 2005, separated by producer Arnon Milchan.

Credit: Kevin Winter/Getty Images

November 2005: Film promoting and getting domestic in Japan

The Hollywood couple grew cozier throughout 2005. By November, Brangelina was just beginning to morph into the power family it came to be. Pitt carried Jolie's daughter Zahara through New Tokyo International Airport ahead of press events for Mr and Mrs Smith.

Credit: Koichi Kamoshida/ GETTY Images Credit: Asahi Shimbun/ getty images

January 2006: Going global with Angelina

The pair went beyond Hollywood in the months that followed. Pitt was soon introduced to the world of international humanitarian work. He joined Jolie, then a United Nations goodwill ambassador, to attend the World Economic Forum in Davos, Switzerland.

Credit: eric feferberg via afp/ Getty Images Credit: FABRICE COFFRINI/afp/Getty Images

October 2006: Exploring the world as a family

Later that year, the couple took a trip to a number of developing Asian countries, including Cambodia, the birthplace of son Maddox. The toddler was pictured with his parents riding in a cart through the streets of Mumbai, India.

Credit: Vijayanand Gupta/Hindustan Times via Getty Images

January 2007: Holding it down at the Golden Globes

Brad and Angelina nevertheless stayed loyal to their Hollywood obligations. Red carpet appearances were usually flawless and featured Angelina wearing a long, sleek, neutral-colored gown at the 64th Annual Golden Globe Awards in 2007.

Credit: Chris Haston/NBCU Photo Bank/ getty images

May 2008: The 'Changeling' premiere at Cannes

By this time, Angelina was pregnant with twins Vivienne and Knox, the last of the couple's six children. She wore a looser gown but they still remained flawless at the premiere of Changeling at the Cannes Film Festival in May.

Credit: George Pimentel/WireImage/ getty images

December 2008: Premiere of 'The Curious Case of Benjamin Button'

Brad debuted a new 'stache and Angelina went back to her usual choice of dress later that year, when they attended the premiere of Brad's film, The Curious Case of Benjamin Button, in Westwood, California.

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Credit: GABRIEL BOUYS/AFP/Getty Images

January 2009: New fashion choices, same Brangelina

As they continued working the red carpet, the more seasoned pair explored new looks. Angelina went for an unlikely updo and Brad put on a scarf for the Berlin, Germany premiere of The Curious Case of Benjamin Button.

Credit: Franziska Krug/ getty Images

October 2009: A humanitarian trip to Syria

As Angelina continued her work as a goodwill ambassador to the UN Human Rights Council, Brad came along for more global adventures. Years before the current conflict in Syria, the couple travelled to Damascus and met with an Iraqi refugee family there. They're pictured after the meeting at a nearby hotel.

Credit: Salah Malkawi/Getty Images

February 2010: Watching the Super Bowl with Maddox

Outside of global affairs and Hollywood glamour, Brad and Angelina made time for American sporting events too. They brought Maddox to Super Bowl XLIV at Sun Life Stadium in Miami Gardens, Florida in 2010.

Credit: Alexander Tamargo/Getty Images

December 2010: Premiere of 'The Tourist' In Madrid

That same year, Angelina starred in The Touristalongside Johnny Depp. The couple gave a cheerful display, per usual, at the movie's premiere in Madrid, Spain.

Credit: PIERRE-PHILIPPE MARCOU/AFP/Getty Images

April 2011: 'God of Carnage' performance in LA

Months later, the Hollywood power couple arrived to the Ahmanson Theatre in Los Angeles to watch the opening night performance of the Tony-winning God of Carnage.

Credit: Ryan Miller/Getty Images

December 2011: Premiere of 'In the Land of Blood and Honey'

The pair sported matching dark hues for an appearance at the Hollywood premiere of In the Land of Blood and Honey, Angelina's long-awaited directorial debut. Brad debuted longer locks.

Credit: Todd Williamson/WireImage/ getty images

February 2013: A gala dinner at the Berlin Film Festival

The coupled smiled and glowed at the Cinema for Peace Gala ceremony, held on Day Five of the 62nd Berlin International Film Festival.

Credit: Pascal Le Segretain/Getty Images

Just weeks later, they arrived to the 84th Annual Academy Awards in Hollywood, decked in all black and still glowing.

Credit: Jeffrey Mayer/WireImage/ getty images

July 2013: Promoting 'World War Z' in Tokyo

The entire family came out for a trip to Tokyo in the summer of 2013. Brad was promoting his most recent film, World War Z, in which he played a United Nations investigator. They're pictured arriving at Haneda International Airport.

Credit: YOSHIKAZU TSUNO/afp/Getty Images

June 2014: Rolling through Los Angeles International Airport

The jet-setting clan made another one of their many airport appearances at LAX the following year on June 6.

Credit: GVK/Bauer-Griffin/GC Images/ getty images

Less than a week later, the couple flew to London to tend to Angelina's humanitarian work. They looked at art work being showcased at the Global Summit to End Sexual Violence in Conflict at the ExCel convention center. By this time, Angelina was a special envoy for the United Nations.

Credit: Danny Martindale/ getty images

November 2015: WSJ Magazine's 2015 Innovator Awards

The couple walked the red carpet outside the Museum of Modern Art in New York City for the WSJ Magazine 2015 Innovator Awards.

Credit: Dimitrios Kambouris/Getty Images

The very next day, on Nov. 5, the Hollywood stars would make one of their last red carpet appearances together.

A tuxedo-clad Brad and sequin-wearing Angelina walked the carpet for the Hollywood premiere of By The Sea, a film in which they both starred.

Credit: Jason LaVeris/FilmMagic/ getty images

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